9. Brad Pitt and Angelina Jolie!
Brad and Angelina’s love was built to last a lifetime -or so we thought! The pair first laid eyes on each other while filming Mr. and Mrs. Smith in 2004 but at the time, Brad was still married to Jennifer Aniston. When his divorce was finalised in 2005, the actor wasted no time in hooking up with Angelina who he married in 2014 – but just two years later, she filed for divorce.
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