23. Freddie Prinze Jr. and Sarah Michelle Gellar!
Freddie Prinze Jr. and Sarah Michelle Gellar first laid eyes on each other when they were cast to star in the 1997 classic I Know What You Did Last Summer. The couple tied the knot in 2002 and in the same year they took on the roles of Fred and Daphne in the live action Scooby-Doo film Spooky Island.
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